OSCILLATIONS AND WAVES IN THE BELOUSOV-ZHABOTINSKII REACTION IN A FINITE MEDIUM

Citation
Ja. Leach et al., OSCILLATIONS AND WAVES IN THE BELOUSOV-ZHABOTINSKII REACTION IN A FINITE MEDIUM, Journal of mathematical chemistry, 16(1-2), 1994, pp. 115-124
Citations number
5
Categorie Soggetti
Chemistry,Mathematics
ISSN journal
02599791
Volume
16
Issue
1-2
Year of publication
1994
Pages
115 - 124
Database
ISI
SICI code
0259-9791(1994)16:1-2<115:OAWITB>2.0.ZU;2-T
Abstract
Travelling reaction-diffusion waves are considered in a finite medium. The model considered is a simplified model of the Belousov-Zhabotinsk ii reaction, described mathematically by the two-variable Oregonator. A one-dimensional problem consisting of three regions is considered. R egions I (x less than or equal to 0) and III (x greater than or equal to 1) act as reservoirs with fixed concentrations of the reactant X (t he autocatalyst, hypobromous acid (HBrO2)), where the concentration of X in regions I and III may be different. Region II represents a catal yst-loaded membrane, within which species X can diffuse while species Z (the oxidized form of the metal-ion catalyst (Ce(IV))) is fixed spat ially. The large time behaviour of the system is considered and both s table steady states and periodic spatio-temporal structures are seen.