The combined hyperfine interaction of mercury in a hexagonal close-pac
ked cobalt single crystal was measured using the e(-)-gamma perturbed
angular correlation technique with the Hg-197 and Hg-199 probes, witho
ut applied magnetic field. The magnetic and quadrupole coupling consta
nts of the 5/2(-) levels in both Hg-197 and Hg-199 were measured with
extremely high precision, omega(L)(Hg-197)=951(9) Mrad/s, omega(L) (Hg
-199)=1039(10) Mrad/s, v(Q) (Hg-197)=3.7(5) MHz and v(Q) (Hg-199)=32(2
) MHz. Using the well-known g factors and quadrupole moments of the re
spective levels, the magnetic hyperfine field, \H-hf(HgCo)\=581(12) kG
, and the electric field gradient, \V-zz(HgCo)\=2.0(3)x10(17) V/cm(2),
were derived. The importance of using these hyperfine probes for stud
ying the microscopic structure of cobalt-based multilayers is introduc
ed and discussed.