THE INTRAMOLECULAR ENE REACTION OF (PROP-2-ENYL)-2-XI-HYDROXY-5-ALPHA-CHOLESTAN-3-ONE

Authors
MARPLES BA SPILLING CD
Citation
Ba. Marples et Cd. Spilling, THE INTRAMOLECULAR ENE REACTION OF (PROP-2-ENYL)-2-XI-HYDROXY-5-ALPHA-CHOLESTAN-3-ONE, Tetrahedron, 50(47), 1994, pp. 13461-13468
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
47
Year of publication
1994
Pages
13461 - 13468
Database
ISI
SICI code
0040-4020(1994)50:47<13461:TIERO(>2.0.ZU;2-7
Abstract
The title unsaturated acyloin undergoes the relatively low temperature (110 degrees C) intramolecular ene reaction to give the 2,5-ethano-ac yloin (17) which rearranges to the 3,5-ethano-isomer (16).