A FREE-RADICAL APPROACH TO CYCLOPENTANONE AND SPIROCYCLIC SYSTEMS - DEVELOPMENT OF A 1,5-ALLYLIC ABSTRACTION-CYCLIZATION SEQUENCE

Authors
PARSONS PJ CADDICK S
Citation
Pj. Parsons et S. Caddick, A FREE-RADICAL APPROACH TO CYCLOPENTANONE AND SPIROCYCLIC SYSTEMS - DEVELOPMENT OF A 1,5-ALLYLIC ABSTRACTION-CYCLIZATION SEQUENCE, Tetrahedron, 50(47), 1994, pp. 13523-13532
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
47
Year of publication
1994
Pages
13523 - 13532
Database
ISI
SICI code
0040-4020(1994)50:47<13523:AFATCA>2.0.ZU;2-L
Abstract
A novel free radical approach to cyclopentanone and spirocyclic ring s ystems is described. This work illustrates the potential of the 1, 5 a llylic abstration-cyclisation reaction and demonstrates the applicatio n of the sequence to systems in which alternative radical cyclisation pathways can be envisaged.