THE STRUCTURE OF DIHYDROXONIUM ALKANEDISU LFONATES

Citation
P. Sartori et al., THE STRUCTURE OF DIHYDROXONIUM ALKANEDISU LFONATES, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 49(11), 1994, pp. 1467-1472
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
09320776
Volume
49
Issue
11
Year of publication
1994
Pages
1467 - 1472
Database
ISI
SICI code
0932-0776(1994)49:11<1467:TSODAL>2.0.ZU;2-8
Abstract
The crystal structures of methanedisulfonic acid- (1) and 1,2-ethandis ulfonic acid-dihydrate (2) have been determined from single crystal X- ray diffraction at T = 145 K (for 1) and T = 125 K (for 2). It has bee n found, that both acids exist in an ionic form as dihydroxonium sulfo nates, but differ in the geometry of the sulfonate groups and in the p ositions of the hydrogen atoms at the oxonium ions.