Angle resolved core level studies of the Si 2p and W 4f levels have be
en carried out on the (110)surface of a WSi2 single crystal using sync
hrotron radiation. Surface shifted components have been revealed both
in the Si 2p and W 4f spectra. Investigations were carried out at two
different annealing temperatures. The results indicate Si enrichment a
t the surface, and a larger enrichment after the higher temperature an
neals. The reactivity upon initial oxygen exposure was investigated. S
trong Si oxidation was observed but chemically shifted W 4f components
could also be detected.