REMARKABLE RATE ENHANCEMENT IN CO INSERTION INTO PD-C BOND BY GENERATING CATIONIC ORGANOPALLADIUM COMPLEXES [PDR(S)L(2)]- (R=ALKYL GROUP, S=ACETONE, L=PHOSPHINE-LIGANDS) FROM NEUTRAL MONOORGANOPALLADIUM COMPLEXES [PDR(X)L(2)] (X=HALIDE)(BF4)

Authors
KAYAKI Y KAWATAKA F SHIMIZU I YAMAMOTO A
Citation
Y. Kayaki et al., REMARKABLE RATE ENHANCEMENT IN CO INSERTION INTO PD-C BOND BY GENERATING CATIONIC ORGANOPALLADIUM COMPLEXES [PDR(S)L(2)]- (R=ALKYL GROUP, S=ACETONE, L=PHOSPHINE-LIGANDS) FROM NEUTRAL MONOORGANOPALLADIUM COMPLEXES [PDR(X)L(2)] (X=HALIDE)(BF4), Chemistry Letters, (11), 1994, pp. 2171-2174
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
11
Year of publication
1994
Pages
2171 - 2174
Database
ISI
SICI code
0366-7022(1994):11<2171:RREICI>2.0.ZU;2-A
Abstract
Removal of the halide ligand X in PdR(X)L(2) with AgBF4 generates solv ent-coordinated cationic organopalladium complexes [PdR(s)L(2)]BF4 whi ch show much higher reactivities for CO insertion than the parent neut ral complexes.