DESIGN AND SYNTHETIC APPLICATIONS OF NEW HETEROMETALLACYCLES

Citation
Am. Echavarren et al., DESIGN AND SYNTHETIC APPLICATIONS OF NEW HETEROMETALLACYCLES, Bulletin des Societes chimiques belges, 103(9-10), 1994, pp. 549-558
Citations number
125
Categorie Soggetti
Chemistry
ISSN journal
00379646
Volume
103
Issue
9-10
Year of publication
1994
Pages
549 - 558
Database
ISI
SICI code
0037-9646(1994)103:9-10<549:DASAON>2.0.ZU;2-B
Abstract
The reaction of cyclic anhydrides with Ni(O) complexes lead to the for mation of nickelacycles by oxidative addition followed by decarbonylat ion. The preparation of chiral nickelacycles from anhydrides derived f rom amino acids and their reactivity is described. The formation of ne w heteropalladacycles by C-H activation or transmetallation reactions and their reactivity will be also discussed.