RADIOLYSIS OF TETRAZOLIUM SALTS IN POLYVINYL-ALCOHOL

Citation
Zk. Kriminskaya et al., RADIOLYSIS OF TETRAZOLIUM SALTS IN POLYVINYL-ALCOHOL, High energy chemistry, 25(4), 1991, pp. 280-285
Citations number
15
Journal title
ISSN journal
00181439
Volume
25
Issue
4
Year of publication
1991
Pages
280 - 285
Database
ISI
SICI code
0018-1439(1991)25:4<280:ROTSIP>2.0.ZU;2-#
Abstract
The radiation chemical yields of formazans were measured in binary sys tems containing polyvinyl alcohol and tetrazolium salts as additives; it was established that they are more than half of the yields of radic als in pure polyvinyl alcohol. The ESR spectra of the indicated system s were measured at various temperatures, and the relative changes in t he radical concentrations were determined. It was suggested that the i ncrease in the concentration of single radicals at T > 400 K is due to the participation of radical pairs in the reaction.