The radiation chemical yields of formazans were measured in binary sys
tems containing polyvinyl alcohol and tetrazolium salts as additives;
it was established that they are more than half of the yields of radic
als in pure polyvinyl alcohol. The ESR spectra of the indicated system
s were measured at various temperatures, and the relative changes in t
he radical concentrations were determined. It was suggested that the i
ncrease in the concentration of single radicals at T > 400 K is due to
the participation of radical pairs in the reaction.