STUDY OF THE PRINCIPLES OF LIQUID-PHASE HYDRODECHLORINATION OF ORGANOCHLORINE COMPOUNDS ON A PD C CATALYST/

Authors
SIMAKOVA IL SEMIKOLENOV VA
Citation
Il. Simakova et Va. Semikolenov, STUDY OF THE PRINCIPLES OF LIQUID-PHASE HYDRODECHLORINATION OF ORGANOCHLORINE COMPOUNDS ON A PD C CATALYST/, Kinetics and catalysis, 32(4), 1991, pp. 892-895
Citations number
9
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
32
Issue
4
Year of publication
1991
Part
2
Pages
892 - 895
Database
ISI
SICI code
0023-1584(1991)32:4<892:SOTPOL>2.0.ZU;2-5
Abstract
The influence of the nature of R in organochlorine compounds R-Cl on t he rate of hydrogenolysis of the C-Cl bond was investigated under comp arable conditions on a Pd/C catalyst. The rate of hydrodechlorination of substituted chlorobenzenes was found to be correlated with the Hamm ett sigma-constant of the substituent. Electron donor substituents fac ilitate hydrogenolysis of the C-Cl bond.