NONEQUILIBRIUM VIBRATIONAL, ATTACHMENT AND DISSOCIATION KINETICS OF HCL IN XECL SELFSUSTAINED LASER DISCHARGES

Authors
LONGO S CAPITELLI M GORSE C DEMYANOV AV KOCHETOV IV NAPARTOVICH AP
Citation
S. Longo et al., NONEQUILIBRIUM VIBRATIONAL, ATTACHMENT AND DISSOCIATION KINETICS OF HCL IN XECL SELFSUSTAINED LASER DISCHARGES, Applied physics. B, Photophysics and laser chemistry, 54(3), 1992, pp. 239-245
Citations number
18
Journal title
Applied physics. B, Photophysics and laser chemistry → ACNP
ISSN journal
07217269
Volume
54
Issue
3
Year of publication
1992
Pages
239 - 245
Database
ISI
SICI code
0721-7269(1992)54:3<239:NVAADK>2.0.ZU;2-8
Abstract
The vibrational kinetics of HCl in a Ne-buffered XeCl selfsustained la ser discharge is self-consistently calculated by coupling the vibratio nal master equation with the chemical one, the Boltzmann equation for electron transport and the circuit equations. The results show the lim its of the classical simplified schemes of HCl vibrational kinetics us ed in the literature. Problems connected with the neglection of HCl de pletion instabilities in the calculations are discussed using a parall el resistor network model.