We report non-linear dielectric measurements in the KTaO3:Nb system (x
(Nb) less than or equal to 0.05) The non-linear susceptibility diverge
s at low temperatures and reaches maximum values in the intermediate r
ange (0.0075 less than or equal to x(Nb) less than or equal to 0.92).
To account for this extremum non linearity, we propose a model of temp
erature dependent clusters which fits with a number of experimental re
ports. We also suggest that this model may be applied to the related c
ompounds SrTiO3:Ca and KTaO3:Na.