SYNTHESIS OF SOME ALKYL METAL SELENOLATO COMPLEXES OF ZINC, CADMIUM AND MERCURY - X-RAY CRYSTAL-STRUCTURE OF ME, HG, SE(2,4,6-PR(I)3C6H2)

Authors
BOCHMANN M COLEMAN AP POWELL AK
Citation
M. Bochmann et al., SYNTHESIS OF SOME ALKYL METAL SELENOLATO COMPLEXES OF ZINC, CADMIUM AND MERCURY - X-RAY CRYSTAL-STRUCTURE OF ME, HG, SE(2,4,6-PR(I)3C6H2), Polyhedron, 11(5), 1992, pp. 507-512
Citations number
27
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
11
Issue
5
Year of publication
1992
Pages
507 - 512
Database
ISI
SICI code
0277-5387(1992)11:5<507:SOSAMS>2.0.ZU;2-O
Abstract
The metal dialkyls MR2 (M = Zn, R = Me, Et, Pr(n), Pr(i); M = Cd, R = Me) react with the sterically hindered selenol 2,4,6-Pr(i)3C6H2SeH(Ar' SeH) under mild conditions to give the complexes [RM(SeAr')]4, whereas the less bulky mesitylene selenol gives the poorly soluble metal bis( selenolato) complexes. MeHgNO3 reacts with Ar'SeH to give MeHg(SeAr') whose crystal structure was determined.