STATISTICAL STUDY OF STRUCTURAL MANIFESTATION OF MUTUAL INFLUENCE OF LIGANDS .3. EQUATORIAL AXIAL INTERACTIONS IN ISOTHIOCYANATO NICKEL(II)COMPLEXES

Authors
JONA E KOZISEK J KOMAN M BOCA R
Citation
E. Jona et al., STATISTICAL STUDY OF STRUCTURAL MANIFESTATION OF MUTUAL INFLUENCE OF LIGANDS .3. EQUATORIAL AXIAL INTERACTIONS IN ISOTHIOCYANATO NICKEL(II)COMPLEXES, Polyhedron, 11(5), 1992, pp. 573-579
Citations number
45
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
11
Issue
5
Year of publication
1992
Pages
573 - 579
Database
ISI
SICI code
0277-5387(1992)11:5<573:SSOSMO>2.0.ZU;2-V
Abstract
Equatorial-axial interactions of ligands in solid nickel(II) complexes have been studied. It was proved by theoretical analysis and statisti cal methods that there exists an approximately linear correlation, R(a ) vs R(e), in solid isothiocyanate complexes with the chromophore [NiN 6], i.e. the mean interatomic distances in axial directions (R(a)) and those in the equatorial plane (R(e)) are mutually dependent.