STRUCTURE OF BIS(ETHYLENEDITHIO)TETRATHIAFULVALENIUM TRIBROMODICUPRATE(I), (BEDT-TTF- COORDINATION OF THE ORGANIC RADICAL CATION TO THE METAL-IONS()CUI2BR3 )
Mb. Inoue et al., STRUCTURE OF BIS(ETHYLENEDITHIO)TETRATHIAFULVALENIUM TRIBROMODICUPRATE(I), (BEDT-TTF- COORDINATION OF THE ORGANIC RADICAL CATION TO THE METAL-IONS()CUI2BR3 ), Journal of the Chemical Society, Chemical Communications, (6), 1992, pp. 515-516
X-Ray crystal analysis has revealed that two sulfur atoms of a bis(eth
ylenedithio)tetrathiafulvalene radical cation, BEDT-TTF+, are coordina
ted to copper(I) atoms in a -Cu-Br-Cu-(mu-Br)2-Cu- Chain, in which eac
h copper atom has a distorted tetrahedral coordination with a sulfur a
tom and three bromine atoms.