Vp. Kuprin et al., PSI-FACTOR AS A POSSIBILITY FOR PREDICTING THE ADSORPTION BEHAVIOR OFORGANIC-SUBSTANCES, Soviet electrochemistry, 27(6), 1991, pp. 676-681
A method was presented for estimating the surface activity of organic
compounds at the electrode/solution interface in different solvents wh
ich involves a consideration of the interactions between the adsorbate
molecules in bulk on one hand and between the solvent molecules on th
e other hand. The psi-factor was selected as the criterion for these i
nteractions. Experimental data were reported which confirm this approa
ch.