This paper investigates the effects of magnetic fields on the evolutio
n and spectral appearance of unstable radiative shocks. In this work,
a detailed treatment of the ionization evolution, the photoionizing ra
diation and its transfer through the gas, is coupled to a one-dimensio
nal magnetohydrodynamics scheme. The cushioning effect of the magnetic
field on the formation of secondary shocks in the postshock cooling f
low is clearly demonstrated by our results. The field strengths requir
ed to suppress shock formation are at least a factor two greater than
predicted by linear stability analysis. Thus a field strength, transve
rse to the flow, of 9-mu-G is required to suppress shock formation beh
ind a 175 km s-1 shock, travelling into a density of 1 cm-3. Inclusion
of the magnetic field results in realistic pressures and densities in
the cool, postshock photoionized shell. This allows us to follow the
dynamics of the evolving photoionization zone where much of the low ex
citation optical radiation is emitted. We discuss characteristic featu
res in the spectra of unstable shocks and describe spectral diagnostic
s, based on the optical and UV line ratios and spatial intensity distr
ibutions, for their identification.