STIMULATED SOFT ELECTRON-SPIN ECHO ENVELOPE MODULATION SPECTROSCOPY

Citation
Ej. Hustedt et al., STIMULATED SOFT ELECTRON-SPIN ECHO ENVELOPE MODULATION SPECTROSCOPY, The Journal of chemical physics, 96(7), 1992, pp. 4954-4962
Citations number
11
ISSN journal
00219606
Volume
96
Issue
7
Year of publication
1992
Pages
4954 - 4962
Database
ISI
SICI code
0021-9606(1992)96:7<4954:SSEEEM>2.0.ZU;2-4
Abstract
An improved technique of electron spin echo envelope modulation (ESEEM ) spectroscopy using soft pulses is proposed. It is functionally relat ed to the standard three-pulse stimulated echo experiment, but has an improved bandwidth. The general class of soft-ESEEM experiments is ana lyzed theoretically by using a product operator formalism. The predict ed features are verified experimentally, in particular, the lack of bl ind spots and the observation of high modulation frequencies.