FORMATION AND STABILIZATION OF PD(III) IN PRESENCE OF THE PORPHYRINATO-TYPE LIGAND BILIRUBIN

Authors
GENCHEVA G BOBEV S MITEWA M
Citation
G. Gencheva et al., FORMATION AND STABILIZATION OF PD(III) IN PRESENCE OF THE PORPHYRINATO-TYPE LIGAND BILIRUBIN, Research of chemical intermediates, 23(2), 1997, pp. 101-107
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Research of chemical intermediates → ACNP
ISSN journal
09226168
Volume
23
Issue
2
Year of publication
1997
Pages
101 - 107
Database
ISI
SICI code
0922-6168(1997)23:2<101:FASOPI>2.0.ZU;2-N
Abstract
Formation of transient Pd(III) species was established in the course o f PdCl42--bilirubin (BR) reaction in basic-water medium. Using the EPR method the formation of an octahedral low-spin PdL.2H(2)O complex was proved exhibiting an anisotropic 2-component EPR spectrum (g(perpendi cular to) = 2.007 and g(parallel to) = 1.998) and effective magnetic m oment mu(eff) = 1.7 BM.