Ms. Suseelan, SYNTHESIS OF TAILOR-MADE -IMINO-1,4,5,6-TETRAHYDRO-1,3,5-TRIAZINE-6-THIONES, Research of chemical intermediates, 23(2), 1997, pp. 155-159
Reaction of 1-amidino-3-arylthioureas (1) with aryl isothiocyanates yi
elded -imino-1,4,5,6-tetrahydro-1,3,5-triazine-6-thiones (3) which con
tained the more electron releasing aryl substituent at the ring nitrog
en. The reaction of the S-benzyl derivatives of (1) with aryl isothioc
yanates could be directed to give the same type of triazinethione deri
vatives but with the desired aryl substituent at the ring nitrogen.