I. Safarik et Op. Strausz, THE THERMAL-DECOMPOSITION OF HYDROCARBONS .3. POLYCYCLIC N-ALKYLAROMATIC COMPOUNDS, Research of chemical intermediates, 23(2), 1997, pp. 179-195
The pyrolysis of the polycyclic n-alkylaromatic compounds, n-alkylpyre
nes, methyl-anthracenes and n-alkylnaphthalenes is reviewed. The types
and distributions of the decomposition products and also the mechanis
ms proposed for their formation are described. The theoretical calcula
tions published on the feasibility of the unique elementary hydrogen t
ransfer step, radical hydrogen transfer, are also discussed.