Picosecond time- and energy-resolved photoluminescence (PL) spectrosco
py is used to investigate hot carrier dynamics in GaAs epilayer struct
ures grown on silicon substrates. The existence of biaxial stress aris
ing from the thermal expansion difference between GaAs and Si substrat
es alters the valence band of GaAs epilayer structures on Si. Using th
e radiative transitions from electrons in donor (Si, 10(16) cm-3) stat
es to separated valence bands in a 2-mu-m GaAs epilayer on Si, energy
relaxation of thermalized hot holes is studied. Different electron ene
rgy relaxation dynamics are observed in thin and wide modulation Be-do
ped GaAs-AlGaAs multiple quantum wells grown on Si substrates, arising
from different valence subband structures.