Vl. Barsukov et al., DISTRIBUTION OF U, TH, AND K IN GRANITES OF THE AUE AND EIBENSTOCK MASSIFS, ERZGEBIRGE, GERMANY, Geohimia, (12), 1996, pp. 1157-1174
Samples from mine workings and drill holes were used to study the dist
ribution of U, Th, and K in the Aue granitic massif over a vertical ex
tent of nearly 2.5 km and in some granites of the Eibenstock massif do
wn to a depth of 250 m from their gently dipping roof. In the inner zo
nes of the granites, at a depth of 1-1.5 km below the present-day surf
ace, the original content of U and Th is 35-40 ppm, and the U/Th ratio
in the unaltered granites is close to unity. Toward the surface, the
granites become increasingly oxidized (as indicated by the Fe oxidatio
n coefficient), the primary distribution of the radiogenic elements is
disturbed (according to fission-track studies), and the abundances of
U and Th decrease sharply. For example, in the Aue massif, the averag
e U content decreases nearly eightfold upward, and the Th content decr
eases nearly sevenfold. Enormous amounts of U and Th-hundreds and thou
sands of tons-were leached from the granite of the Aue dome (whose top
is exposed) under the influence of Neogene and Paleogene epigenetic p
rocesses. These amounts are much greater than the uranium reserves hos
ted within the large Schlema deposit, which is marginal to this massif
. In the weaker oxidized granites of the eastern slope of the Eibensto
ck massif, which are separated from the surface by a 500-1000-m layer
of gneissic schists, the epigenetic losses of U and Tn are less signif
icant. Computer modeling indicates that Fe oxidation of granites influ
ences the scale of U scavenging at 150 and 25 degrees C. The K content
(its initial value is estimated at 5.4 wt % K2O) does not vary with t
he approach to the surface, but substantially depends on the distance
from the contact of the granites, which was intersected by pathways of
mass exchange between the melt and the environment during the emplace
ment of the granitic massifs. The original abundances of U, Th, and K
in the deep zones of the Erzgebirge pluton enable the radiogenic heat
generation of the granites to be evaluated at similar to 15 HPU, while
most intrusions of granitoid composition are characterized by a value
of 4.8 HPU.