OCCURRENCE OF WOODRUFFITE, (ZN, MN-2 H2O,HETAEROLITE, ZNMN2O4, AND HYDROHETAEROLITE, HZNMN2-XO4, OF SUPERGENE ORIGIN IN A SKARN OF MONT CHEMIN (VALAIS, SWITZERLAND)(2)MN3+ 4O7.1)
N. Meisser et Ea. Perseil, OCCURRENCE OF WOODRUFFITE, (ZN, MN-2 H2O,HETAEROLITE, ZNMN2O4, AND HYDROHETAEROLITE, HZNMN2-XO4, OF SUPERGENE ORIGIN IN A SKARN OF MONT CHEMIN (VALAIS, SWITZERLAND)(2)MN3+ 4O7.1), Schweizerische Mineralogische und Petrographische Mitteilungen, 73(1), 1993, pp. 11-19
Woodruffite, (Zn, Mn+2)Mn3+4O7 - 1-2 H2O, a todorokite-related mineral
, hetaerolite ZnMn2O4 and hydrohetaerolite. HZnMn2-xO4, are described
in a quartz-calcite Alpine vein cutting a magnetite and sulfide-bearin
g skarn in the Chez Larze Mine, Mont Chemin (Valais, Switzerland). Woo
druffite occurs as millimeter-to centimeter-botryoidal masses composed
of microcrystals. Hetaerolite is the rarest mineral and forms small e
quigranular crystals around concretions of woodruffite. Hydrohetaeroli
te is optically very similar to woodruffite and occurs as an alteratio
n product of hetaerolite. These minerals have a supergene origin.