STUDIES ON MECHANISM OF REACTION OF DICHL OROCARBENE WITH TETRAPHENYLCYCLOPENTADIENONE

Authors
GU WX WANG HX PAN YM HUAN ZW CHENG JP
Citation
Wx. Gu et al., STUDIES ON MECHANISM OF REACTION OF DICHL OROCARBENE WITH TETRAPHENYLCYCLOPENTADIENONE, Gaodeng xuexiao huaxue xuebao, 18(2), 1997, pp. 238-241
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Gaodeng xuexiao huaxue xuebao → ACNP
ISSN journal
02510790
Volume
18
Issue
2
Year of publication
1997
Pages
238 - 241
Database
ISI
SICI code
0251-0790(1997)18:2<238:SOMORO>2.0.ZU;2-4
Abstract
The reaction of dichlorocarbene with tetraphenylcyclone (1) resulted i n carbon monoxide and gem-dichloro compound (3) together with dichloro oxirane (4) and adduct (5), The aromatic structure of carbonyl Ylide a nd its twist geometry led to deoxygenation to be the main reaction pat hway.