STUDIES ON CONFORMATIONAL ORDER OF Q-CDS COMPLEX LB FILM

Citation
Lj. Wang et al., STUDIES ON CONFORMATIONAL ORDER OF Q-CDS COMPLEX LB FILM, Gaodeng xuexiao huaxue xuebao, 18(2), 1997, pp. 281-284
Citations number
10
Categorie Soggetti
Chemistry
ISSN journal
02510790
Volume
18
Issue
2
Year of publication
1997
Pages
281 - 284
Database
ISI
SICI code
0251-0790(1997)18:2<281:SOCOOQ>2.0.ZU;2-3
Abstract
Under the conditions of the higher surface pressure and deposition spe ed, ordered organic/CdS nanaparticles complex film was prepared by the reaction of cadmium stearate and H2S. ''All trans'' conformation of - CH2- can be kept well alter reaction which is thought to form nanoorde r organic-inorganic superlattice material, Bragg(001) diffraction peak s can be observed by means of X-ray diffract ion related to 5.02 nm of the long period, The order property of LE complex film was shown acco rding to the result of infrared spectrum, The band gap (E(g)) of CdS n anoparticle is 3.46 eV which increases 1.04 eV comparable to that of t he bulk material (2.42 eV) from the result of UV-V is spectrum.