Intramolecular contrast of C60 molecules has been observed by scanning
tunneling microscopy at 4.5 K on a C60 fullerite thin film sample. Th
is result provides strong evidence for the freezing of the rotational
motion of C60 molecules at low temperatures as recently proposed by re
finement analysis of neutron diffraction data. Different intramolecula
r patterns are observed. Interpretation of these patterns is suggested
by assigning them to carbon ring structures of the C60 molecules in v
arious orientations.