LIGAND-EXCHANGE AND MOLECULAR AGGREGATION OF AN AG-SN HETEROBIMETALLIC COMPLEX - FIRST STRUCTURAL CHARACTERIZATION OF AN AG-SN BOND

Authors
FINDEIS B GADE LH SCOWEN IJ MCPARTLIN M
Citation
B. Findeis et al., LIGAND-EXCHANGE AND MOLECULAR AGGREGATION OF AN AG-SN HETEROBIMETALLIC COMPLEX - FIRST STRUCTURAL CHARACTERIZATION OF AN AG-SN BOND, Inorganic chemistry, 36(6), 1997, pp. 960
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
36
Issue
6
Year of publication
1997
Database
ISI
SICI code
0020-1669(1997)36:6<960:LAMAOA>2.0.ZU;2-N
Abstract
A direct Ag-Sn bond has been established for the first time by X-ray c rystallography for the dimeric complex [MeSi{SiMe(2)N(p-Tol)}3SnAg](2) (4) [d(Ag-Sn)=2.6567(7) Angstrom], which is the product of a phosphin e ligand redistribution reaction of MeSi{SiMe(2)N(p-Tol)}3SnAg(PPh(3)) (2)