PREPARATION AND CHARACTERIZATION OF A HOMOLEPTIC VANADIUM(III) AMIDE COMPLEX AND ITS TRANSFORMATION INTO TERMINAL CHALCOGENIDE DERIVATIVES [(3,5-ME(2)PH)ADN](3) V=E (E=S, SE, AD EQUALS ADAMANTYL)

Authors
RUPPA KBP DESMANGLES N GAMBAROTTA S YAP G RHEINGOLD AL
Citation
Kbp. Ruppa et al., PREPARATION AND CHARACTERIZATION OF A HOMOLEPTIC VANADIUM(III) AMIDE COMPLEX AND ITS TRANSFORMATION INTO TERMINAL CHALCOGENIDE DERIVATIVES [(3,5-ME(2)PH)ADN](3) V=E (E=S, SE, AD EQUALS ADAMANTYL), Inorganic chemistry, 36(6), 1997, pp. 1194-1197
Citations number
37
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
36
Issue
6
Year of publication
1997
Pages
1194 - 1197
Database
ISI
SICI code
0020-1669(1997)36:6<1194:PACOAH>2.0.ZU;2-I
Abstract
Reaction of VCl3(THF)(3) with (3,5-Me(2)Ph)AdNLi . Et(2)O (Ad = adaman tyl) yields the homoleptic vanadium complex [(3,5-Me(2)Ph)AdN](3) V (1 ), which reacts with chalcogens E (E = S, Se) to yield diamagnetic ter minal chalcogenide derivatives [(3,5-Me(2)Ph)AdN](3)V=E [E = S (3a), S e (3b)] Crystal data for 1 and 3a are as follows. 1: C54H72N3V, fw 814 .09, triclinic P (1) over bar, a = 10.441(1) Angstrom, b = 11.648(4) A ngstrom, c = 19.321(2) Angstrom, alpha = 83.69(2)degrees, beta = 83.89 (1)degrees, gamma = 82.42(2)degrees, Z = 2. 3a: C(5)4H(72)N(3)VS . 1/2 Et(2)O, fw 883.25, monoclinic C2/c, a = 43.400(9) Angstrom, b = 11.744 (3) Angstrom, c = 20.705(4) Angstrom, beta = 113.05(1)degrees, Z = 8.