SYNTHESIS OF OPTICALLY-ACTIVE SECONDARY ALLYLIC ALCOHOLS FROM ALLYLSILANES VIA SUCCESSIVE ASYMMETRIC DIHYDROXYLATION (AD) AND PETERSON OLEFINATION REACTIONS

Authors
OKAMOTO S TANI K SATO F SHARPLESS KB ZARGARIAN D
Citation
S. Okamoto et al., SYNTHESIS OF OPTICALLY-ACTIVE SECONDARY ALLYLIC ALCOHOLS FROM ALLYLSILANES VIA SUCCESSIVE ASYMMETRIC DIHYDROXYLATION (AD) AND PETERSON OLEFINATION REACTIONS, Tetrahedron letters, 34(15), 1993, pp. 2509-2512
Citations number
17
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
15
Year of publication
1993
Pages
2509 - 2512
Database
ISI
SICI code
0040-4039(1993)34:15<2509:SOOSAA>2.0.ZU;2-J
Abstract
Optically active, secondary allylic alcohols can be prepared from ally lic silanes by the successive asymmetric dihydroxylation and Peterson olefination reactions. The Effects of trialkylsilyl groups on the outc ome of the AD reaction on vinyl and allyl silanes are also discussed.