C-S BOND-CLEAVAGE ROUTES TO THE TITANIUM-SULFIDE COMPLEXES (CPTI)(6)(MU(3)-S)(4)(MU(3)-O)(4) AND (CPTI)(4)(MU(3)-S)(3)(MU(2)-S)(MU(2)-SET)(2) (CP=ETA-C5H5)

Authors
FIRTH AV STEPHAN DW
Citation
Av. Firth et Dw. Stephan, C-S BOND-CLEAVAGE ROUTES TO THE TITANIUM-SULFIDE COMPLEXES (CPTI)(6)(MU(3)-S)(4)(MU(3)-O)(4) AND (CPTI)(4)(MU(3)-S)(3)(MU(2)-S)(MU(2)-SET)(2) (CP=ETA-C5H5), Inorganic chemistry, 36(6), 1997, pp. 1260
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
36
Issue
6
Year of publication
1997
Database
ISI
SICI code
0020-1669(1997)36:6<1260:CBRTTT>2.0.ZU;2-T
Abstract
Thermolysis at 80 degrees C of reaction mixtures of CpTiMeCl(2), thiol , and base results in C-S bond cleavage and the isolation of two new T i-sulfide species (CPTi)(4)(mu(3)-S)(3)(mu(2)-S)(mu(2)-SEt)(2) and (Cp Ti)(6-) (mu(3)-S)(4)(mu(3)-O)(4) (Cp = eta-C5H5), both of which have b een crystallographically characterized. (Cp ligands are omitted from t he diagram.)