CRYSTAL-STRUCTURES OF THE ISOMORPHOUS PROTOTYPIC OXO-CENTERED TRINUCLEAR COMPLEXES [CR3O(OOCCH3)(6)(H2O)(3)]CL-CENTER-DOT-6H(2)O AND [FE3O(OOCCH3)(6)(H2O)(3)]CL-CENTER-DOT-6H(2)O

Authors
ANSON CE BOURKE JP CANNON RD JAYASOORIYA UA MOLINIER M POWELL AK
Citation
Ce. Anson et al., CRYSTAL-STRUCTURES OF THE ISOMORPHOUS PROTOTYPIC OXO-CENTERED TRINUCLEAR COMPLEXES [CR3O(OOCCH3)(6)(H2O)(3)]CL-CENTER-DOT-6H(2)O AND [FE3O(OOCCH3)(6)(H2O)(3)]CL-CENTER-DOT-6H(2)O, Inorganic chemistry, 36(6), 1997, pp. 1265
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
36
Issue
6
Year of publication
1997
Database
ISI
SICI code
0020-1669(1997)36:6<1265:COTIPO>2.0.ZU;2-Z
Abstract
The two compounds [Cr3O(OOCCH3)(6)(H2O)(3)]Cl . 6H(2)O and [Fe3O(OOCCH 3)(6)(H2O)(3)]Cl . 6H(2)O are the prototypes of the general class of t rinuclear ''basis carboxylates''. New single-crystal X-ray structure d eterminations show that the two compounds are strictly isomorphous, wi th little disorder, and make it possible to quantify the extents of di stortion of the molecules from idealized trigonal geometry.