ACTIVITY OF ACTIVE-CARBON SUPPORTED FERRIC CATALYST IN AMMONIA-SYNTHESIS

Authors
NARKIEWICZ U ARABCZYK W KALUCKI K
Citation
U. Narkiewicz et al., ACTIVITY OF ACTIVE-CARBON SUPPORTED FERRIC CATALYST IN AMMONIA-SYNTHESIS, Przemysl Chemiczny, 72(3), 1993, pp. 96-98
Citations number
21
Journal title
Przemysl Chemiczny → ACNP
ISSN journal
00332496
Volume
72
Issue
3
Year of publication
1993
Pages
96 - 98
Database
ISI
SICI code
0033-2496(1993)72:3<96:AOASFC>2.0.ZU;2-J
Abstract
The ammonia synthesis catalysts obtained by impregnation of charcoal w ith the solution of Fe(NO3)3 and K4 [Fe(CN)6] have been studied. Sampl e activities were measured in an integral react or under the pressure of 10 M Pa and their phase composition was studied using the X-ray dif fractometry method. Two forms of iron have been found - the crystallic alpha-Fe and the well dispersed iron undetectable by X-ray diffractom etry. The most active catalysts have the K:Fe molar ratio of about 1:5 , The greatest amount of high dispersed iron for that composition has been found.