ON THE FORMATION MECHANISM OF HEXAFLUOROPROPYLENE OXIDE IN LOW-TEMPERATURE LIQUID-PHASE OXIDATION OF HEXAFLUOROPROPYLENE BY MOLECULAR-OXYGEN

Authors
SHAPOVALOV VV POLUEKTOV VA
Citation
Vv. Shapovalov et Va. Poluektov, ON THE FORMATION MECHANISM OF HEXAFLUOROPROPYLENE OXIDE IN LOW-TEMPERATURE LIQUID-PHASE OXIDATION OF HEXAFLUOROPROPYLENE BY MOLECULAR-OXYGEN, Reaction kinetics and catalysis letters, 48(2), 1992, pp. 375-378
Citations number
6
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
48
Issue
2
Year of publication
1992
Pages
375 - 378
Database
ISI
SICI code
0133-1736(1992)48:2<375:OTFMOH>2.0.ZU;2-Y
Abstract
The effect of initiation rate (dose-rate of gamma-radiation) the forma tion rate of hexafluoropropylene oxide has been studied. Experimental data confirm that the epoxide forms in the reaction R-O-C3F6.--> -->R. + C3F6O, as contrasted to the generally accepted fragmentation of bet a-peroxyalkyl radicals R-O-O-C3F6. --> RO. + C3F6O.