DETERMINATION OF ALUMINUM ELECTRONEGATIVITY IN NEW AMBIENT-TEMPERATURE ACIDIC MOLTEN-SALTS BASED ON 3-BUTYL-1-METHYLIMIDAZOLIUM CHLORIDE AND ALET3-XCLX (X = 0-3) BY H-1 NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY

Authors
CHAUVIN Y DIMARCOVANTIGGELEN F OLIVIER H
Citation
Y. Chauvin et al., DETERMINATION OF ALUMINUM ELECTRONEGATIVITY IN NEW AMBIENT-TEMPERATURE ACIDIC MOLTEN-SALTS BASED ON 3-BUTYL-1-METHYLIMIDAZOLIUM CHLORIDE AND ALET3-XCLX (X = 0-3) BY H-1 NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY, Journal of the Chemical Society. Dalton transactions, (7), 1993, pp. 1009-1011
Citations number
19
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
7
Year of publication
1993
Pages
1009 - 1011
Database
ISI
SICI code
0300-9246(1993):7<1009:DOAEIN>2.0.ZU;2-K
Abstract
Aluminium electronegativity in molten salts based on 3-butyl-1-methyli midazolium chloride and AlEtCl2, AlEt2Cl, AlEt3 and mixtures of AlEtCl 2 and AlCl3 has been determined by the modified Dailey-Shoolery equati on using H-1 NMR spectroscopy. For Al to 3-butyl-1-methylimidazolium c hloride molar ratios between 1 : 1 and 3 : 1 there is a linear relatio nship between the aluminium electronegativity of the anionic species p resent in the melts and the molar composition.