ON THE REACTIONS OF [RUCL2(PPH3)3] WITH THIA CROWN ETHERS - MOLECULAR-STRUCTURES OF [RUCL2(PPH3)([9]ANES3)] ([9]ANES3 = 1,4,7-TRITHIACYCLONONANE) AND [RUCL(PPH3)([14]ANES4)CLO4 ([14]ANES4 = 1,4,8,11-TETRATHIACYCLOTETRADECANE)

Authors
ALCOCK NW CANNADINE JC CLARK GR HILL AF
Citation
Nw. Alcock et al., ON THE REACTIONS OF [RUCL2(PPH3)3] WITH THIA CROWN ETHERS - MOLECULAR-STRUCTURES OF [RUCL2(PPH3)([9]ANES3)] ([9]ANES3 = 1,4,7-TRITHIACYCLONONANE) AND [RUCL(PPH3)([14]ANES4)CLO4 ([14]ANES4 = 1,4,8,11-TETRATHIACYCLOTETRADECANE), Journal of the Chemical Society. Dalton transactions, (7), 1993, pp. 1131-1135
Citations number
13
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
7
Year of publication
1993
Pages
1131 - 1135
Database
ISI
SICI code
0300-9246(1993):7<1131:OTRO[W>2.0.ZU;2-A
Abstract
The reaction of [RuCl2(PPh3)3] with 1,4,7-trithiacyclononane ([9]aneS3 ) gives the neutral complex [RuCl2(PPh3)([9]aneS3)] while the same com plex with 1,4,8,11-tetrathiacyclotetradecane ([14]aneS4) followed by c hloride-perchlorate metathesis provides the salt cis-[RuCl(PPh3)([14]a neS4)]ClO4. The structures of both complexes have been determined by X -ray crystallography.