N-2(A''(1)SIGMA(G)(-EXCITATION TRANSFER BY N-2() METASTABLE COLLISIONAL DESTRUCTION AND ROTATIONAL)

Quenching and rotational coupling rate coefficients have been measured for the J=4-10, v=0 levels of the a'' 1SIGMA(g)+ metastable state of N2 in collisions with ground state N2. Laser absorption is used to mon itor the population of rotational levels of the a'' 1SIGMA(g)+ state f ollowing depletion of the population of one or more levels by optical pumping to other states. The observed time dependence of the recovery of population of the perturbed level and the collision induced growth and decay of the populations of adjacent levels are interpreted in ter ms of quenching to other electronic levels and excitation exchange amo ng adjacent rotational levels. For the J=6, v=0 level of the a'' 1SIGM A(g)+ state the rate coefficients extrapolated to zero discharge curre nt at 300 K are 2.3 +/- 0.1 x 10(-6) m3/s for electronic quenching and 1.1 +/- 0.6 X 10(-16) m3/S for excitation transfer to the J=4 and J=8 levels in collisions with N2. Very similar rate coefficents were obta ined for the J=4, 7 and 8 levels.