REACTIONS OF MIXED O,S-ESTERS OF ACIDS OF TRIVALENT PHOSPHORUS WITH SUBSTITUTED 1-CHLOROACETYLENES

Authors
SINYASHIN OG ZUBANOV VA BATYEVA ES
Citation
Og. Sinyashin et al., REACTIONS OF MIXED O,S-ESTERS OF ACIDS OF TRIVALENT PHOSPHORUS WITH SUBSTITUTED 1-CHLOROACETYLENES, Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences, 41(7), 1992, pp. 1264-1265
Citations number
7
Journal title
Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences → ACNP
ISSN journal
10635211
Volume
41
Issue
7
Year of publication
1992
Part
2
Pages
1264 - 1265
Database
ISI
SICI code
1063-5211(1992)41:7<1264:ROMOOA>2.0.ZU;2-E
Abstract
The reactions of mixed O,S-esters of tert-butylthiophosphonous acid an d dithiophosphorous acid with 1-chloro-2-organylacetylenes were studie d. On the basis of them, a convenient method for the synthesis of thio esters of organylethynylthiophosphinic and dithiophosphonic acids, whi ch are undescribed in the literature, was proposed. A difference was f ound in the chemical behavior of the methyl ester of S,S-diethyldithio phosphorous acid by comparison with the corresponding complete esters and thioesters of phosphorous acid in reactions with dichloroacetylene .