REACTION OF 1,2-BORYLPHOSPHINOETHENE WITH THIOCYANATES - MOLECULAR AND CRYSTAL-STRUCTURE OF LTHIO-1,5,2-AZAPHOSPHONIABORATACYCLOHEXA-3,6-DIENE

Authors
ARBUZOV BA NIKONOV GN BALUEVA AS KAMALOV RM STEPANOV GS PUDOVIK MA LITVINOV IA LENSTRA ATH GEISE HJ
Citation
Ba. Arbuzov et al., REACTION OF 1,2-BORYLPHOSPHINOETHENE WITH THIOCYANATES - MOLECULAR AND CRYSTAL-STRUCTURE OF LTHIO-1,5,2-AZAPHOSPHONIABORATACYCLOHEXA-3,6-DIENE, Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences, 41(7), 1992, pp. 1266-1271
Citations number
10
Journal title
Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences → ACNP
ISSN journal
10635211
Volume
41
Issue
7
Year of publication
1992
Part
2
Pages
1266 - 1271
Database
ISI
SICI code
1063-5211(1992)41:7<1266:RO1WT->2.0.ZU;2-0
Abstract
The reaction of 1,2-borylphosphinoethenes with alkylthiocyanates leads to formation of substances having the structure of thio-1,5,2-azaphos phoniaboratacyclohexa-3,6-dienes in the crystal state. The structure o f the compounds has been proven by x-ray diffraction analysis of thio- 1,5,2-azaphosphoniaboratacyclohexa-3,6-diene. The heterocyclic moiety of the molecule is planar within 0.010(2) angstrom. The methylthio gro up lies practically in the plane of the heterocycle.