ALCOHOLYSIS OF HYDRIDESILANES TO GIVE SILYL ETHERS CATALYZED BY RHODACARBORANES CLOSO-3,3-(PH3P)2-3-H-3,1,2-RHC2B9H11 AND CLOSO-3,3-(ETA-2,ETA-3-C7H7CH2)-3,1,2-RHC2B9H11

Authors
ZAKHARKIN LI ZHIGAREVA GG
Citation
Li. Zakharkin et Gg. Zhigareva, ALCOHOLYSIS OF HYDRIDESILANES TO GIVE SILYL ETHERS CATALYZED BY RHODACARBORANES CLOSO-3,3-(PH3P)2-3-H-3,1,2-RHC2B9H11 AND CLOSO-3,3-(ETA-2,ETA-3-C7H7CH2)-3,1,2-RHC2B9H11, Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences, 41(7), 1992, pp. 1284-1285
Citations number
15
Journal title
Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences → ACNP
ISSN journal
10635211
Volume
41
Issue
7
Year of publication
1992
Part
2
Pages
1284 - 1285
Database
ISI
SICI code
1063-5211(1992)41:7<1284:AOHTGS>2.0.ZU;2-6
Abstract
Rhodacarboranes closo-3,3-(Ph3P)2-3-H-3,1,2-RhC2B9H11 and closo-(eta2, eta3-C7H7CH2)-3,1,2-RhC2B9H11 are catalysts for the alcoholysis of hy dridesilanes. Closo-3,3-(eta2, eta3-C7H7CH2)-3,1,2-RhCB9H11 displays g reater activity than closo-3,3-(Ph3P)2-3-H-3,1,2-RhC2B9H11 though both rhodacarboranes catalyze the alcoholysis of hydridesilanes more effic iently than (Ph3P)3RhCl.