M. Holtz et al., CRYOGENIC PRESSURE AND LIFETIME STUDIES OF A DEFECT RELATED EMISSION IN HEAVILY SILICON DOPED GAAS, Physica status solidi. b, Basic research, 198(1), 1996, pp. 199-203
We have used cryogenic high pressure measurements and lifetime studies
to investigate a defect related emission at 1.269 eV in silicon doped
GaAs. The pressure measurements prove that the 1.269 eV photon energy
is relative to the conduction band. This implies a deep defect level
approximate to 0.30 eV above the valence band and an electron capture
process from near the conduction band into tile defect. The defect lev
el moves up in the bandgap at a rate of (23 +/- 3) meV/GPa. Between 20
K and room temperature the defect emission lifetime remains constant
at (9.63 +/- 0.25) ns. while the intensity decreases over this same ra
nge. We explain this surprising result using an intradefect emission p
rocess. These results are consistent with a vacancy related defect lev
el, possibly stemming from a gallium vacancy-silicon at gallium (secon
d-nearest-neighbor) defect complex.