REGIOCHEMICAL SYNTHESIS OF STRAIGHT CHAIN ACIDS BY THE PALLADIUM(II) CATALYZED HYDROCARBOXYLATION OF OLEFINS WITH OXALIC-ACID

Authors
ELALI B ALPER H
Citation
B. Elali et H. Alper, REGIOCHEMICAL SYNTHESIS OF STRAIGHT CHAIN ACIDS BY THE PALLADIUM(II) CATALYZED HYDROCARBOXYLATION OF OLEFINS WITH OXALIC-ACID, Journal of molecular catalysis, 80(3), 1993, pp. 377-381
Citations number
12
Journal title
Journal of molecular catalysis → ACNP
ISSN journal
03045102
Volume
80
Issue
3
Year of publication
1993
Pages
377 - 381
Database
ISI
SICI code
0304-5102(1993)80:3<377:RSOSCA>2.0.ZU;2-V
Abstract
Olefins react with carbon monoxide and oxalic acid, catalyzed by palla dium acetate in the presence of 1,4-bis(diphenylphosphino)butane, to g ive linear carboxylic acids regioselectively or regiospecifically. Thi s process shows excellent functional group tolerance.