SYNTHESIS OF A NEW CHIRAL PORPHYRIN LIGAND AND ITS MN(III) COMPLEX ASCATALYST IN ASYMMETRIC ALKENE EPOXIDATION

Authors
PROESS G HEVESI L
Citation
G. Proess et L. Hevesi, SYNTHESIS OF A NEW CHIRAL PORPHYRIN LIGAND AND ITS MN(III) COMPLEX ASCATALYST IN ASYMMETRIC ALKENE EPOXIDATION, Journal of molecular catalysis, 80(3), 1993, pp. 395-401
Citations number
19
Journal title
Journal of molecular catalysis → ACNP
ISSN journal
03045102
Volume
80
Issue
3
Year of publication
1993
Pages
395 - 401
Database
ISI
SICI code
0304-5102(1993)80:3<395:SOANCP>2.0.ZU;2-M
Abstract
A new chiral ligand, meso-tetrafenchylidenylmethylporphyrin, as well a s the corresponding manganese(III)porphyrin have been synthesized. The first results on the catalytic asymetric epoxidation of styrenes and of unfunctionalized aliphatic alkenes, using sodium hypochlorite as ox ygen source, are reported.