This paper presents the archaeological contexts and results of analyse
s of slags, surface residues, and earthenware refractories from the th
ird-millennium B.C. site of Goltepe in south-central Turkey. These mat
erials are only part of a workshop/habitation assemblage at the site,
which also includes ore nodules, multifaceted molds, and metal fragmen
ts as well as groundstone tools utilized in ore dressing and beneficia
tion. Twenty-four ceramic fragments of bowl-shaped crucibles were anal
yzed as a representative sample from some 250 examples excavated in th
e 1990 season. Analysis suggests the intentional production of tin met
al by reduction firing of tin oxide (cassiterite, SnO2) in crucibles.
Tin oxide was identified on the interior surfaces of the crucible frag
ments by x-ray fluorescence, x-ray diffraction, scanning electron micr
oscopy coupled with energy dispersive x-ray analysis, and wavelength d
ispersive microprobe analysis. The results of these tests have a direc
t bearing on the question of tin sources in ancient Anatolia.