The overtone lasing performance of the supersonic continuous wave hydr
ogen-fluoride chemical laser at the University of Illinois at Urbana-C
hampaign was optimized by the same set of flow rates that optimized th
e fundamental performance. When the absorption/scattering losses of th
e mirrors were taken into account, an overtone efficiency (the ratio o
f overtone power to maximum fundamental power for the same flow condit
ions) of 70-90% was achieved. The overtone efficiency was a strong fun
ction of medium saturation. There was no significant change in overton
e power and efficiency as the mode volume increased. However, there wa
s an increase in the number of lasing lines and a shift to higher rota
tional (J) lines. Overtone performance was as sensitive to cavity pres
sure as fundamental performance was. There was no significant change i
n overtone efficiency when the method of helium injection was changed.