MICROELECTRODE COMPARATIVE-STUDIES OF THE LI LI+ COUPLE IN LIALCL4/SO2CL2 ELECTROLYTE AND LIALCL4, 3SO2 SOLVATE/

Authors
AUBAY M LOJOU E MESSINA R PERICHON J
Citation
M. Aubay et al., MICROELECTRODE COMPARATIVE-STUDIES OF THE LI LI+ COUPLE IN LIALCL4/SO2CL2 ELECTROLYTE AND LIALCL4, 3SO2 SOLVATE/, Journal of the Electrochemical Society, 140(4), 1993, pp. 879-884
Citations number
22
Journal title
Journal of the Electrochemical Society → ACNP
ISSN journal
00134651
Volume
140
Issue
4
Year of publication
1993
Pages
879 - 884
Database
ISI
SICI code
0013-4651(1993)140:4<879:MCOTLL>2.0.ZU;2-E
Abstract
Inert microelectrode comparative studies of the Li/Li+ couple in both LiAlCl4/SO2Cl2 and LiAlCl4, 3SO2 solvate electrolytes are undertaken u sing chronoamperometry and chronopotentiometry. Lithium deposits grow according to an instantaneous 3D-nucleation process. The solvate prese nts the best behavior regarding faradaic efficiency and corrosion rate of electrodeposited lithium. The SEI layer influence, formed during t he first reduction of the cathodic material before plating the lithium , is discussed.