G. Franz, ROBUST REACTIVE ION ETCHING PROCESSES FOR GAAS ALGAAS/ALAS BY APPLICATION OF STATISTICAL CONCEPTS/, Journal of the Electrochemical Society, 140(4), 1993, pp. 1147-1151
Reactive ion etching of AlGaAs/GaAs was investigated using chlorine-co
ntaining gases. We defined a remarkably stable process exhibiting very
good process parameters: smooth surfaces, rectangular side walls, and
good selectivity against photoresist, but almost no difference in etc
h rates due to a different aluminum content. These response variables
depend on the process parameters RF power, total gas pressure, total g
as flow, and mixing ratio of reactive to nonreactive gases. The etch r
ate mainly depends linearly on dc-bias and the flow of BCl3. The devia
tion from linearity for bias is attributed to the chemical part of mat
erial removal. About three quarters of the observed response variables
can be explained by the chosen model. The inclination angle of the si
de walls which are free of redeposits is almost rectangular to the etc
hed surfaces, which are extremely smooth. This is compared with glow d
ischarges of neutral atoms.