HIGH-PRESSURE COMPACTION OF NANOSIZE CERAMIC POWDERS

High-density ceramic materials from nanosize ceramic powders were prod uced by high pressure under nearly hydrostatic environment up to 5.6 G Pa, on a special configuration in a toroidal-type apparatus, at room t emperature. Attempts to use a common solid pressure transmitting mediu m, as NaCl, resulted in cracked samples. Lead and indium, which have a n extremely low shear strength, proved to be the suitable choices as a pressure-transmitting medium to compact these ceramic materials, in o rder to obtain high-density samples. Transparent amorphous SiO2-gel an d translucent gamma-Al2O3 samples, in bulk, with volumes about 40 mm(3 ), hard and crack-free were obtained. Densities over 90% of full densi ty for the gamma-Al2O3 samples and over 80% for the compacted SiO2-gel samples were obtained. In addition, from the density-pressure curve, the yield strength (sigma) for gamma-Al2O3 was estimated, for the firs t time, as 2.6 GPa. Vickers microhardness values were in the range of 5.7 GPa for the gamma-Al2O3 samples, and 4.0 GPa for the SiO2-gel samp les, under loads of 50 g. An important and practical application of th ese results is the possibility of producing bulk gamma-Al2O3, a new al umina material, which was not possible to prepare before due to the co nversion to ct phase during the normal sintering process. Additionally , specially for SiO2-gel, a very important application of this study i s the possibility of incorporation of organic substances in an inorgan ic matrix, using high pressure at room temperature.