SYNTHESIS OF STERICALLY RIGID MACROCYCLES BY THE USE OF PRESSURE-INDUCED REPETITIVE DIELS-ALDER REACTIONS

Authors
BENKHOFF J BOESE R KLARNER FG
Citation
J. Benkhoff et al., SYNTHESIS OF STERICALLY RIGID MACROCYCLES BY THE USE OF PRESSURE-INDUCED REPETITIVE DIELS-ALDER REACTIONS, Liebigs Annalen, (3), 1997, pp. 501-516
Citations number
73
Categorie Soggetti
Chemistry
Journal title
Liebigs Annalen → ACNP
ISSN journal
09473440
Issue
3
Year of publication
1997
Pages
501 - 516
Database
ISI
SICI code
0947-3440(1997):3<501:SOSRMB>2.0.ZU;2-R
Abstract
Syntheses of syn-dimethanotetrahydroanthracene, -tetracene, and -penta cene derivatives 8a-d, 9a-d, and syn-25 are described. Highly stereose lective, pressure-induced Diels-Alder reactions of the bis-dienophiles 8a and/or 9a with the bis-diene 7 lead to the sterically rigid macroc yles 1a, 2a, and 3a/3b, which have well defined cavities of different sizes([1]).