Equivalent widths of the diffuse interstellar bands (DIBs) lambdalambd
a5780, 5797 and of the interstellar D1 and D2 lines have been measured
on Lick and Canada-France-Hawaii Telescope coude spectrograms of 93 s
tars. Correlations with column densities of H I, H-2, Na I, C I, K I,
and Ti II have led to the following conclusions: (1) the carrier of th
ese DIBs is not produced by the processes based upon H-2 that control
the abundance of carbon diatomics in diffuse clouds: in fact, (2) DIB
column density is instead dependent upon N(H I) and appears not to res
pond to N(H-2) at all; (3) the carrier is not significantly influenced
by the depletion of Ti, regarded as an indicator of whether the solid
grains have been shocked or not; (4) the carrier is not affected by s
hock heating of the gas, believed to be responsible for the appearance
of strong CH+ lines in the Pleiades; (5) DIB strength does not depend
upon the over- or underabundance of the small grains that dominate th
e extinction at 1250 angstrom, or upon the value of R = A(V)/E(B-V); (
6) DIB strength follows a power-law dependence upon N(Na I), N(C I), a
nd N(K I) with exponents of 0.5-0.7, but in most lines of sight is dir
ectly proportional to E(B-V); (7) despite this close correlation, the
carrier of these DIBs in the Orion Nebula does not reside in the solid
particles that produce the reddening. In general it behaves like a fr
ee neutral species in the gas and responds to the ionization level of
the gas as if its ionization/dissociation threshold is somewhat higher
than 5 eV.